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VA;O >E>;>465==O 4> =0DB0;V=C 4>40NBL 0,5 <; :>=F5=B@>20=>W H2SO4 V AC<VH >15@56=> =03@V20NBL ?@8 AB@CHC20==V 4> CB2>@5==O >4=>@V4=>W @V48=8. >BV< AC<VH >E>;>46CNBL, 4>40NBL 1-2 <; 2>48 B0 7=>2C =03@V20NBL. @8 >E>;>465==V 284V;OTBLAO (-=0DB0;V=AC;LD>:8A;>B0. 0;820NBL C ?@>1V@:C 1-2 <; 2>48. >BV< 4>40NBL =04;8H>: 2>48. >A;V4 3. ;0AB82>ABV 0;V70@8=C 0) 70T<>4VO 0;V70@8=C 7 3V4@>:A84>< =0B@VN # ?@>1V@:C 7 8-10 <; 2>48 2=>AOBL 0,02 3 0;V70@8=C, 2<VAB ?@>1V@:8 ?5@5<VHCNBL. > >45@60=>W ACA?5=7VW 4>40NBL 1-2 <; 5%-3> @>7G8=C NaOH. #B2>@NTBLAO V=B5=A82=> 7010@2;5=89 DV>;5B>2>-A8=V9 @>7G8=. 1) 45@60==O 0;V70@8=C 7 9>3> ?>EV4=8E > >45@60=>3> C ?>?5@54=L><C 4>A;V4V @>7G8=C 4>;820NBL 5%-89 @>7G8= HCl. 8?040T >A04 0;V70@8=C C 283;O4V ?;0ABV2FV2. >A;V4 4. 45@60==O D5=>;DB0;5W=C # ?@>1V@FV 7<VHCNBL ?@8 AB@CHC20==V 0,1 3 4@V1=> @>7B5@B>3> DB0;52>3> 0=3V4@84C 7 ?>42V9=>N :V;L:VABN D5=>;C, 0 ?>BV< 4> AC<VHV 4>40NBL 1-2 :@0?;V :>=F5=B@>20=>W H2SO4. <VAB ?@>1V@:8 >15@56=> =03@V20NBL C ?>;C< W ?0;L=8:0 ?@>BO3>< 2-3 E2. 4> @>7?;02;5==O AC<VHV 9 CB2>@5==O B5<=>-G5@2>=>3> 7010@2;5==O. VA;O >AB830==O AC<VHV, I> <VAB8BL D5=>;DB0;5W=, 4>;820NBL ?@8 AB@CHC20==V 5 <; 30@OG>W 2>48. > 3-5 :@0?5;L 2>4=>3> :8A;>3> @>7G8=C D5=>;DB0;5W=C, O:89 =0;820NBL C ?@>1V@:C, 4>40NBL 2 =. @>7G8= NaOH.  O2;OTBLAO <0;8=>25 7010@2;5==O. > >45@60=>3> @>7G8=C 4>40NBL ?> :@0?;OE 2 =. @>7G8= HCl. >7G8= 7=510@2;NTBLAO.  "  " ! 6  !!# >A;V4 1. >7G8==VABL A?8@BV2 C 2>4V  >:@5<V ?@>1V@:8 =0;820NBL ?> 1 <; 5B8;>2>3>, ?@>?V;>2>3>, 1CB8;>2>3>, 0<V;>2>3> A?8@BV2, 5B8;5=3;V:>;N B0 3;VF5@8=C. >40NBL C :>6=C ?@>1V@:C ?> 3 <; 2>48 9 5=5@3V9=> AB@CHCNBL. >A;V4 2. >@V==O A?8@BV2 # D0@D>@>2V G0H:8 =0;820NBL ?> 1...2 <; A?8@BV2, @>7<VICNG8 WE C ?>@O4:C 71V;LH5==O <>;5:C;O@=>W <0A8 (5B8;>289, ?@>?V;>289, 1CB8;>289, 0<V;>289). V4?0;NNBL A?8@B8 B0 ?>@V2=NNBL E0@0:B5@ ?>;C< O. >A;V4 3. 8O2;5==O 2>48 C A?8@BV # D0@D>@>2C G0H:C 2<VICNBL ?@81;87=> 1 3 :@8AB0;VG=>3>  EMBED Equation.2  V =03@V20NBL 9>3> =0 ?>;C< W ?0;L=8:0 4> 7=8:=5==O 1;0:8B=>3> 7010@2;5==O. # ACEC ?@>1V@:C =0;820NBL 2...3 <; 5B8;>2>3> A?8@BC 9 C=>AOBL C =L>3> >45@60=89 1572>4=89  EMBED Equation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quation.2  V 2-3 <; 10%-3> @>7G8=C  EMBED Equation.2 . > >45@60=>3> >A04C 4>;820NBL :V;L:0 :@0?5;L 5B8;5=3;V:>;N 9 AC<VH ?5@5<VHCNBL. >A;V4 ?>2B>@NNBL V7 3;VF5@8=><. >A;V4 6. ;0AB82>ABV D5=>;C 0) >7G8==VABL D5=>;C C 2>4V B0 9>3> :8A;89 E0@0:B5@ # ?@>1V@:C 2<VICNBL 1 3 :@8AB0;VG=>3> D5=>;C V =0;820NBL 45 <; 2>48.  >45@60=89 2>4=89 @>7G8= D5=>;C >?CA:0NBL A8=V9 ;0:<CA>289 ?0?V@5FL. 1) 45@60==O D5=>;OBC =0B@VN #<VAB ?@>1V@:8 7 ?>?5@54=L>3> 4>A;V4C ?5@5<VHCNBL 4> CB2>@5==O 5<C;LAVW V 4>40NBL ?> :@0?;OE 10%-89 @>7G8=  EMBED Equation.2 . > @>7G8=C D5=>;OBC =0B@VN 4>40NBL 10%-89 @>7G8= HCl. 2) 70T<>4VO D5=>;C 7 E;>@84>< 70;V70 () # ?@>1V@:C =0;820NBL 1 <; 2%-3> @>7G8=C D5=>;C V 4>40NBL 12 :@0?;V 2%-3> @>7G8=C  EMBED Equation.2 .  "  " ! 7 >:A>A?>;C:8 >A;V4 1. :8A;5==O D>@<0;L453V4C (O:VA=V @50:FVW =0 0;L453V48): 0) 0<V0G=8< @>7G8=>< 3V4@>:A84C A@V1;0 !?>G0B:C 4>1@5 28<820NBL ?@>1V@:C. ;O FL>3> 2 ?@>1V@FV >15@56=> :8? OBOBL 1-2 E2. 1;87L:> 5 <; 10%-3> @>7G8=C  EMBED Equation.2 , 0 ?>BV< :V;L:0 @07V2 <8NBL WW 48AB8;L>20=>N 2>4>N. # 28<8BV9 ?@>1V@FV 3>BCNBL 0<V0G=89 @>7G8= 3V4@>:A84C A@V1;0  EMBED Equation.2 : 4> 2...3 <; 1%-3> @>7G8=C  EMBED Equation.2  4>40NBL ?> :@0?;OE ?@8 AB@CHC20==V 5%-9 @>7G8= 0<V0:C 4>B8, ?>:8 =5 @>7G8=8BLAO >A04, O:89 A?>G0B:C CB2>@82AO. 04;8H>: 0<V0:C C @>7G8=V 7=86CT GCB;82VABL @50:FVW. > >45@60=>3> 15710@2=>3> @>7G8=C 4>40NBL 1 <; 40%-3> @>7G8=C D>@<0;L453V4C 9 >?CA:0NBL ?@>1V@:C =0 :V;L:0 E28;8= C 2>4O=C 10=N 7 B5<?5@0BC@>N 2>48 60...70>!. 0 ABV=:0E ?@>1V@:8 ?>ABC?>2> 284V;OTBLAO H0@ A@V1;0 C 283;O4V 475@:0;0, V=>4V A@V1;> 284V;OTBLAO C 283;O4V B5<=>3> >A04C. VA;O 70:V=G5==O 4>A;V4C 2V4@07C 6 <8NBL ?@>1V@:C 20%-=8< @>7G8=>< 07>B=>W :8A;>B8, V @>7G8=, I> CB2>@82AO, 7;820NBL C A?5FV0;L=C A:;O=:C. 1) 3V4@>:A84>< <V4V () > ?@>1V@:8 7 40%-8< @>7G8=>< D>@<0;L453V4C 4>40NBL 2 <; 10%3> @>7G8=C  EMBED Equation.2  V ?@8 AB@CHC20==V ?> :@0?;OE 2%-9 @>7G8=  EMBED Equation.2  4> CB2>@5==O =57=8:0NG>W 7028AV. 5@E=N G0AB8=C @V48=8 =03@V20NBL 4> 70:8?0==O. ;0:8B=89 :>;V@ 7<V=NTBLAO =0 6>2B89 (>A04), 0 ?>BV< =0 G5@2>=89 (>A04). >A;V4 2. V4=>H5==O 0F5B>=C 4> 3V4@>:A84C <V4V () >2B>@NNBL ?>?5@54=V9 4>A;V4, 0;5 70<VABL D>@<0;L453V4C 15@CBL 0F5B>=. >A;V4 3. 70T<>4VO 0;L453V4V2 V :5B>=V2 V7 3V4@>AC;LDVB>< =0B@VN # 42V ?@>1V@:8 =0;820NBL ?> 1 <; =0A8G5=>3> @>7G8=C NaHSO3. @8 5=5@3V9=><C ?5@5<VHC20==V C ?5@HC ?@>1V@:C 4>40NBL 10 :@0?5;L D>@<0;L453V4C, 2 4@C3C 10 :@0?5;L 0F5B>=C. @8 >E>;>465==V ?@>1V@>: C AB0:0=V 7 ;L>4>< 28?040T 1V;89 :@8AB0;VG=89 >A04. /:I> >A04 2V4@07C =5 CB2>@NTBLAO, B> 28:;8:0NBL :@8AB0;V70FVN ?>B8@0==O< A:;O=>W ?0;8G:8 ?> ABV=:0E ?@>1V@:8. >A;V4 4. >;L>@>20 @50:FVO =0 0;L453V48 7 DC:A8=AV@G8AB>N :8A;>B>N # ?@>1V@:C =0;820NBL 1 <; @>7G8=C DC:A8=AV@G8AB>W :8A;>B8 V 4>40NBL :V;L:0 :@0?5;L 10%-3> @>7G8=C D>@<0;L453V4C. <VAB ?@>1V@:8 5=5@3V9=> ?5@5<VHCNBL. '5@57 45O:89 G0A C ?@>1V@FV 7 O2;OTBLAO G5@2>=>-DV>;5B>25 7010@2;5==O. >BV< C ?@>1V@:C 4>;820NBL 0.5 <; :>=F5=B@>20=>W  EMBED Equation.2   DV>;5B>25 7010@2;5==O 7<V=NTBLAO =0 A8=T.  "  " ! 8   !" >A;V4 1. ;0AB82>ABV >FB>2>W :8A;>B8: 0) 70T<>4VO 7 <03=VT< V 7 >:A84>< <V4V (II) # ?@>1V@:C =0;820NBL 1-2 <; >FB>2>W :8A;>B8, 4>40NBL B@>E8 <5B0;52>3> <03=VN V 70:@820NBL ?@>1V@:C ?@O<>N 307>2V42V4=>N B@C1:>N 7 2V4BO3=CB8< :V=F5<. '5@57 45O:89 G0A ?V4?0;NNBL 307, I> 284V;OTBLAO. > 0,1 3 >:A84C <V4V (II), 2<VI5=>3> 2 ?@>1V@:C, 4>;820NBL 1-2 <; >FB>2>W :8A;>B8, ?>BV< ?@>1V@:C >15@56=> =03@V20NBL. 25@B0NBL C203C =0 :>;V@ @>7G8=C. 1) 70T<>4VO 7 :0@1>=0B>< =0B@VN > :V;L:>E :@0?5;L 10%-3> @>7G8=C :0@1>=0BC =0B@VN 4>;820NBL :V;L:0 :@0?5;L :>=F5=B@>20=>W >FB>2>W :8A;>B8. >A;V4 2. 45@60==O A:;04=8E 5DV@V2: 0) FB>2>-5B8;>2>3> 5DV@C # ?@>1V@FV 7<VHCNBL 2 <; :>=F5=B@>20=>W >FB>2>W :8A;>B8, 2 <; 5B8;>2>3> A?8@BC 9 0,5 <; :>=F5=B@>20=>W  EMBED Equation.2 . !C<VH >15@56=> AB@CHCNBL V ?@>1V@:C =03@V20NBL =0 2>4O=V9 10=V ?@>BO3>< 10 E2. @>1V@:C >E>;>46CNBL, 4>40NBL ?@81;87=> 0,5 <; 2>48 B0 =0A8G5=89 @>7G8=  EMBED Equation.2 . 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